An efficient synthesis of valienamine via ring-closing metathesis |
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| Authors: | Chang Young-Kil Lee Bo-Young Kim Dong Jun Lee Gwan Sun Jeon Heung Bae Kim Kwan Soo |
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| Affiliation: | Center for Bioactive Molecular Hybrids and Department of Chemistry, Yonsei University, Seoul 120-749, Korea. |
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| Abstract: | An efficient synthesis of valienamine is described. Valienamine was synthesized starting from commercially available 2,3,4,6-tetra-O-benzyl-D-glucose in nine steps, using ring-closing metathesis of (4S,5S,6S)-4,5,6-tribenzyloxy-7-(benzyloxymethyl)octa-1,7-dien-3-ol as a key step. |
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