| Some Attempts to Employ the Singlet Oxygen Generated from H2O2 |
| |
| 作者姓名： | 金红霞 刘鹤华 伍贻康 |
| |
| 作者单位： | StateKeyLaboratoryofBio-organic＆NaturalProductsChemistry,ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shanghai200032,China |
| |
| 基金项目： | the National Natural Science Foundation of China (Nos. 20025207, 20272071, 20372075, 20321202), the Qinghaosu Science and Technology Foundation, the Chinese Academy of Sciences (No. KGCX2-SW-209) and the Major State Basic Resear |
| |
| 摘 要： | Some attempts to employ the singlet oxygen generated from molybdate-catalyzed decomposition of hydrogen peroxide are presented. Reduction of ascaridole with diimide is also described, along with the preliminary results of the cleavage study using Fe-cysteinate as a simple model for Fe-S type redox species. There were strong indications that S-alkylation occurred as observed in similar cleavage of the potent antimalarial qinghaosu.
|
| 关 键 词： | 过氧化氢 纯态氧 分解反应 反应机理 |
Some Attempts to Employ the Singlet Oxygen Generated from H_2O_2 |
| |
| JIN,Hong-Xia LIU,He-HuaWU,Yi-Kang State Key Laboratory of Bio-organic & Natural Products Chemistry.Some Attempts to Employ the Singlet Oxygen Generated from H2O2[J].Chinese Journal of Chemistry,2004,22(9):999-1002. |
| |
| Authors: | JIN Hong-Xia LIU He-HuaWU Yi-Kang State Key Laboratory of Bio-organic & Natural Products Chemistry |
| |
| Institution: | JIN,Hong-Xia LIU,He-HuaWU,Yi-Kang State Key Laboratory of Bio-organic & Natural Products Chemistry,Shanghai Institute of Organic Chemistry,Chi-nese Academy of Sciences,Shanghai 200032,China |
| |
| Abstract: | Some attempts to employ the singlet oxygen generated from molybdate-catalyzed decomposition of hydrogen peroxide are presented. Reduction of ascaridole with diimide is also described, along with the preliminary results of the cleavage study using Fe-cysteinate as a simple model for Fe-S type redox species. There were strong indica-tions that S-alkylation occurred as observed in similar cleavage of the potent antimalarial qinghaosu. |
| |
| Keywords: | peroxide singlet oxygen free radical cleavage mechanism |
| 本文献已被 CNKI 维普 等数据库收录！ |
