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| 取代四甲基环戊二烯基钌羰基化合物的合成及晶体结构(英文) | |
| 引用本文： | 马志宏,赵明霞,林丽枝,郑学忠,林 进. 取代四甲基环戊二烯基钌羰基化合物的合成及晶体结构(英文)[J]. 无机化学学报, 2010, 26(6): 1121-1124 |
| 作者姓名： | 马志宏 赵明霞 林丽枝 郑学忠 林 进 |
| 作者单位： | 1. 河北师范大学化学与材料科学学院,石家庄050016;河北医科大学基础医学院,石家庄050017 2. 河北师范大学化学与材料科学学院,石家庄,050016 3. 华北制药康欣有限公司,石家庄,050015 |
| 基金项目： | 河北省自然科学基金资助项目，河北师范大学博士启动基金资助项 |
| 摘 要： | The ligands (C5Me4R) [R =n-Butyl (1), Benzyl (2), PhMe-2 (3)] reacted with Ru3(CO)12 in refluxing xylene to give corresponding new substituted tetramethylcyclopentadienyl diruthenium metal carbonyl complexes [(η5-C5Me4R)Ru(CO)( μ-CO)]2 [R=n-Butyl (4), Benzyl (5), PhMe-2 (6)], respectively. The three new complexes were characterized by elemental analysis, IR and 1H NMR spectra. The crystal structure of complex 5 was determined by single crystal X-ray diffraction. The X-ray crystal structure of complex 5 confirms the structure with bridging and terminal CO groups. CCDC: 709601. |
| 关 键 词： | 羰基钌； 二聚物； 结构； 环戊二烯基 |
Synthesis and Crystal Structure of Substituted Tetramethylcyclopentadienyl Diruthenium Metal Carbonyl Complexes |
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| MA Zhi-Hong,ZHAO Ming-Xi,LIN Li-Zhi,ZHENG Xue-Zhong and LIN Jin. Synthesis and Crystal Structure of Substituted Tetramethylcyclopentadienyl Diruthenium Metal Carbonyl Complexes[J]. Chinese Journal of Inorganic Chemistry, 2010, 26(6): 1121-1124 | |
| Authors: | MA Zhi-Hong ZHAO Ming-Xi LIN Li-Zhi ZHENG Xue-Zhong LIN Jin |
| Affiliation: | College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016; College of Basic Medicine, Hebei Medical University, Shijiazhuang 050017,College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016,North China Pharmaceutical Kangxin Co., Ltd, Shijiazhuang 050015,College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016 and College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016 |
| Abstract: | The ligands (C5Me4R) [R=n-Butyl (1), Benzyl (2), PhMe-2 (3)] reacted with Ru3(CO)12 in refluxing xylene to give corresponding new substituted tetramethylcyclopentadienyl diruthenium metal carbonyl complexes [(η5-C5Me4R)Ru(CO)(μ-CO)]2 [R=n-Butyl (4), Benzyl (5), PhMe-2 (6)], respectively. The three new complexes were characterized by elemental analysis, IR and 1H NMR spectra. The crystal structure of complex 5 was determined by single crystal X-ray diffraction. The X-ray crystal structure of complex 5 confirms the structure with bridging and terminal CO groups. CCDC: 709601. |
| Keywords: | ruthenium carbonyl dimer structure cyclopentadienyl |
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