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Conduction and diffusion in exchanged montmorillonite clays
Institution:1. Royal Brompton Hospital, London, UK;2. National Heart and Lung Institute, Imperial College London, UK;3. Cardiovascular Research Unit, Royal Brompton & Harefield NHS Foundation Trust, Imperial College London, UK;4. UCL Institute of Cardiovascular Science, University College London, UK
Abstract:The temperature dependences for conductivities and 1H NMR relaxation times are reported for homionic (exchanged) montmorillonite clays. Ionic conductivity in the interlayer region is primarily protonic (H+), arising from the Brønsted acidity of hydrated interlayer cations. Hydrogens outside the hydration shell appear to undergo translation by chemical exchange.
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