Conduction and diffusion in exchanged montmorillonite clays |
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Institution: | 1. Royal Brompton Hospital, London, UK;2. National Heart and Lung Institute, Imperial College London, UK;3. Cardiovascular Research Unit, Royal Brompton & Harefield NHS Foundation Trust, Imperial College London, UK;4. UCL Institute of Cardiovascular Science, University College London, UK |
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Abstract: | The temperature dependences for conductivities and 1H NMR relaxation times are reported for homionic (exchanged) montmorillonite clays. Ionic conductivity in the interlayer region is primarily protonic (H+), arising from the Brønsted acidity of hydrated interlayer cations. Hydrogens outside the hydration shell appear to undergo translation by chemical exchange. |
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