Ir-catalyzed direct borylation at the 4-position of pyrene |
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Authors: | Zhiqiang Liu Yuanyuan Wang Ying Chen Jie Liu Qi Fang Christian Kleeberg Todd B Marder |
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Affiliation: | State Key Laboratory of Crystal Materials, Shandong University , Jinan, 250100, China. |
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Abstract: | The first direct borylation of a C-H bond at the 4-position of pyrene was achieved using [Ir(COD)Cl](2)/dtbpy as the catalyst precursor and B(2)pin(2) as the boron source. The position-related photophysical properties of pyrene derivatives are reported. |
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