Preparation and characterization of mixed amido,carboxylato or thiazolato carbonyl(phosphine)technetium(I) complexes |
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| Authors: | Andrea Marchi Roberto Rossi Adriano Duatti Gian Luigi Zucchini Luciano Magon |
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| Institution: | (1) Istituto Chimico, Laboratorio di Chimica Nucleare e Radiochimica, Università di Ferrara, Italy |
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| Abstract: | Summary The complex Tc(PPh3)2(CO)3Cl] reacts with the lithium salt of amido-carboxylato- and thiazolato-derivatives to give the new complexes (Ar= C6H4Me-p or C6H4OMe-p), Tc(PPh3)2(CO)2(amt1,2)] amt1=anion of 2-(methylamino)thiazole; amt2=anion of 2-4-methoxyphenylamino(thiazole)] and Tc(PPh3)2(CO)2- (R = Ph2CH, PhCH2 or CCl3). The compounds have been characterized by elemental analysis, and i.r. and1H n.m.r. spectra. |
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