| Asymmetric total synthesis of (+)-1-deoxy-6-epi-castanospermine |
| |
| 引用本文： | 徐一鸣,周维善. Asymmetric total synthesis of (+)-1-deoxy-6-epi-castanospermine[J]. 中国化学, 1998, 16(1): 34-44. DOI: 10.1002/cjoc.19980160107 |
| |
| 作者姓名： | 徐一鸣 周维善 |
| |
| 作者单位： | Shanghai Institute of Organic Chemistry，Chinese Academy of Sciences，Shanghai 200032，China，Shanghai Institute of Organic Chemistry，Chinese Academy of Sciences，Shanghai 200032，China |
| |
| 基金项目： | Project (29732061) supported by the National Natural Science Foundation of China and the State Key Laboratory of Bio-Organic & Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences. |
| |
| 摘 要： | (+)-1-Deoxy-6-epi-castanospermine was asymmetrically synthesized in ten steps from α-furfuryl amine derivative 6 in 2.9% overall yield. The kinetic resolution of α-furfuryl amine derivative 6 and Sharpless AD reaction of 14 were used as key steps.
|
Asymmetric total synthesis of (+)-1-deoxy-6-epi-castanospermine |
| |
| XU,Yi-Ming ZHOU,Wei-Shan. Asymmetric total synthesis of (+)-1-deoxy-6-epi-castanospermine[J]. Chinese Journal of Chemistry, 1998, 16(1): 34-44. DOI: 10.1002/cjoc.19980160107 |
| |
| Authors: | XU Yi-Ming ZHOU Wei-Shan |
| |
| Affiliation: | XU,Yi-Ming ZHOU,Wei-ShanShanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China |
| |
| Abstract: | (+)-l-Deoxy-6-epi-castanospermine was asymmetrically synthesized in ten steps from a-furfuryl amine derivative 6 in 2.9% overall yield. The kinetic resolution of a-furfuryl mine derivative 6 and Sharpless AD reaction of 14 were used as key steps. |
| |
| Keywords: | Kinetic resolution total synthesis (+)-1-deoxy-6-epi-castanosperrnine |
| 本文献已被 CNKI 等数据库收录！ |
