Coordination chemistry of the bis(trifluoromethylsulfonyl)imide anion: molecular interactions in room temperature ionic liquids |
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| Authors: | Williams D Bridget Stoll Michael E Scott Brian L Costa David A Oldham Warren J |
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| Affiliation: | Nuclear Materias Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA. |
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| Abstract: | Room temperature ionic liquids composed of bis(trifluoromethylsulfonyl)imide anions and 1,3-ethylmethylimidazolium (EMI) cations are shown to stabilize monomeric ligand deficient transition metal complexes via four distinct binding modes: monodentate nitrogen or oxygen coordination and/or bidentate oxygen-oxygen' or nitrogen-oxygen coordination (eta1-N, eta1-O, eta2-O,O' and eta2-N,O). |
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