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High‐resolution slice selection NMR for the measurement of CO2 diffusion under non‐equilibrium conditions
Authors:Jesse Allen  Krishnan Damodaran
Institution:1. National Energy Technology Laboratory, Pittsburgh, PA, USA;2. Biological Sciences, California Institute of Technology, Pasadena, CA, USA;3. Department of Chemistry, University of Pittsburgh, Pittsburgh, PA, USA
Abstract:We present a simple and an efficient approach using spatially selective NMR to investigate solvation and diffusion of CO2 in ionic liquids. The techniques demonstrated here are shown as novel and effective means of studying solvated gas dynamics under non‐equilibrium conditions without the need for conventional high power gradients. Copyright © 2014 John Wiley & Sons, Ltd.
Keywords:ionic liquids  gas diffusion  slice selection NMR  concentration gradient
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