Mixed-ligand and binuclear complexes of oxovanadium(IV) |
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Authors: | Bhavna J. Pandya Pabitra K. Bhattacharya |
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Affiliation: | (1) Department of Chemistry, Faculty of Science, M. S. University of Baroda, 390 002 Baroda, India |
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Abstract: | Summary Mixed ligand complexes of the type [VOLA]ClO4 where L=5-bromosalicylaldehyde (L) or 5-nitrosalicylaldehyde (L) and A=2, 2-dipyridyl (A) or 1, 10-phenanthroline (A) have been prepared. Treatment of the mononuclear complexes, [VOLA]ClO4, withp-phenylenediamine (ppd) orm-phenylenediamine (mpd) yielded homobinuclear [VOLA-NC6H4N-LAVO](ClO4)2, complexes, which were characterised by elemental analyses, spectra, magnetic susceptibility and molar conductance measurements. |
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