| 烯丙醇电还原自由基中间产物的ESR研究 |
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| 引用本文： | 张敬东,汪风珍.烯丙醇电还原自由基中间产物的ESR研究[J].电化学,1996,2(3):343-345. |
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| 作者姓名： | 张敬东 汪风珍 |
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| 作者单位： | 湖南大学化学化工系，中南工业大学测试中心，中国科学院化学研究所，长沙水利电力学院化学系 |
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| 基金项目： | 中国科学院化学研究所分子动态与稳态结构国家重点实验室资助 |
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| 摘 要： | 烯丙醇电还原自由基中间产物的ＥＳＲ研究张敬东，旷亚非，黄树坤，谢乃贤（湖南大学化学化工系，长沙４１００８２）汪风珍，陈德文（中南工业大学测试中心，长沙４１００８３）（中国科学院化学研究所，北京１０００８０）Ｈｏｒａｎｙｉ［１］、陈剑［２］等人对酸性水...
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| 关 键 词： | 烯丙醇 电还原 自由基 ESR 自旋捕集技术 |
An ESR Study of Free Radicals in Electroreduction Process of Allyl Alcohol |
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| Zhang Jindong,Kuang Yafei,Huang Shukun,Xie Naixian.An ESR Study of Free Radicals in Electroreduction Process of Allyl Alcohol[J].Electrochemistry,1996,2(3):343-345. |
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| Authors: | Zhang Jindong Kuang Yafei Huang Shukun Xie Naixian |
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| Abstract: | Electrochemical-ESR technique with spin trap phenyl-t-butyl nitrone(PBN)was used to study the intermediates of electroreduction of allyl alcohol at platinized platinum electrode in acidic alcohol-aqua solution. Hydrogen and allyl group and(or)propyl group radicals were identified by a hyperfine spectrum of the radical adducts,and that provided a direct evidence for the presence of these radicals in the electroreduction of allyl alcohol. |
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| Keywords: | Allyl alcohol Electroreduction Electrochemieal-ESR Spin trapping |
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