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Synthesis and extraction properties of oxathiacrown compounds containing benzyl groups
Authors:N A Rezekina  E V Rakhmanov  E V Lukovskaya  A A Bobylyova  A A Abramov  V A Chertkov  A V Khoroshutin  A V Anisimov
Institution:(1) M. V. Lomonosov Moscow State University, Moscow, 119899, Russia
Abstract:8-Benzyl-1.4-dioxa-7,10-dithiacyclododecane and 11-benzyl-1,4,7-trioxa-10,13-dithiacyclopentadecane were obtained by the interaction of (2,3-dibromo-1-propyl)benzene with 1,8-dimercapto-3,6-dioxaoctane and 1,11-dimercapto-3,6,9-trioxaundecane. The extracting ability of the obtained compounds has been studied in relation to Sr2+ and Pb2+ ions from aqueous solutions in the presence of anions of various degrees of hardness with determination of the metal content by a radiometric method. __________ Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 244–249, February, 2006.
Keywords:dithia-12(15)-crown-4(5) ethers  Sr2+ and Pb2+ ions  complex-formation  extraction
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