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Reaction of nitroalkane in the presence of solid bases prepared under various conditions
Authors:Adam Górecki and Wincenty Skupi&#;ski
Institution:(1) Division of Highenergetic Materials, Faculty of Chemistry, Warsaw University of Technology(Politechnika), Noakowskiego 3, 000-664 Warszawa, Poland
Abstract:Alumina for chromatography (acidic, basic and neutral), magnesia and sodium-doped magnesia calcined at 350, 450, 550, 650 and 750oC for 4 h were used as solid bases to catalyze the synthesis of 1-nitro-2-butanol from nitromethane and propionaldehyde (Henry reaction). This revised version was published online in June 2006 with corrections to the Cover Date.
Keywords:nitroalkanes  Solid bases  Henry reaction
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