Recent Developments on Catalytic Applications of Nano-Crystalline Magnesium Oxide |
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Authors: | Venkat Reddy Chintareddy M Lakshmi Kantam |
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Institution: | (1) 1311 Gilman Hall, Department of Chemistry, Iowa State University, Ames, IA 50011, USA;(2) Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, Hyderabad, 500607, India |
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Abstract: | Nanocrystalline metal oxides, MgO, CuO, ZnO, TiO2 as catalysts or catalyst supports have been received much attention in the recent years, especially nanocrystalline magnesium
oxide (NAP-MgO) has been used as a recyclable catalyst for Wittig, Wadsworth–Emmons, aza-Michael, Baylis–Hillman, Strecker,
Aldol, Claisen-Schmidt condensation and other useful organic reactions. In general, it is reported that nanocrystalline magnesium
oxide shows better activity in many organic reactions. These high reactivities are due to high surface areas combined with
unusually reactive morphologies. The nanomaterials were also explored as supports to make supported metal catalysts for the
organic reactions. The higher activity of these catalysts was studied partly to understand the mechanism of the reaction,
the putative reaction pathways were preliminarily presented with the help of spectroscopic support, XPS, silicon, and phosphorus
NMR spectroscopy. The catalysts are recovered and reused for several cycles. These catalytic systems are expected to contribute
to the development of benign chemical processes. |
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Keywords: | |
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