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原料对自由落下床中生物质与煤共热解行为的影响
引用本文:魏立纲,张丽,徐绍平.原料对自由落下床中生物质与煤共热解行为的影响[J].燃料化学学报,2011,39(10):728-734.
作者姓名:魏立纲  张丽  徐绍平
作者单位:1.State Key Laboratory of Fine Chemicals, Department of Chemical Engineering, Dalian University of Technology, ; Dalian 116012, China; 2.School of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China
基金项目:National Natural Science Foundation of China(50776013); National High Technology Research and Development Program(863 Program,2008AA05Z407); Program for Liaoning Excellent Talents in University(2009R10)
摘    要:在500~700℃和生物质混合比0~100%(质量分数)条件下,利用自由落下床反应器考察原料对生物质与煤共热解行为的影响.所用煤原料为大雁褐煤(DY)和铁法烟煤(TF),而生物质原料为农业废弃物秸秆(LS)和木材加工余料白松木屑(SD).结果表明,即使在自由落下床中停留时间短的条件下,生物质与煤共热解的协同效应仍然发生...

关 键 词:生物质    共热解
收稿时间:2010-09-28

Effects of feedstock on co-pyrolysis of biomass and coal in a free fall reactor
WEI Li-gang,ZHANG Li,XU Shao-ping.Effects of feedstock on co-pyrolysis of biomass and coal in a free fall reactor[J].Journal of Fuel Chemistry and Technology,2011,39(10):728-734.
Authors:WEI Li-gang    ZHANG Li  XU Shao-ping
Institution:WEI Li-gang1,2,ZHANG Li1,XU Shao-ping1(1.State Key Laboratory of Fine Chemicals,Department of Chemical Engineering,Dalian University of Technology,Dalian 116012,China,2.School of Light Industry and Chemical Engineering,Dalian Polytechnic University,Dalian 116034,China)
Abstract:Effects of feedstock on the co-pyrolysis of biomass and coal were investigated in a free fall reactor at 500℃~700℃ with biomass blending ratio of 0~100%(mass ratio). The selected coal samples were Dayan brown coal (DY) and Tiefa bituminous coal (TF), and the biomass samples were agricultural residues legume straw (LS) and woody residues pine sawdust (SD). The results indicate that the synergy can occur even in a short gas residence time during the co-pyrolysis of biomass and coal in a free-fall reactor. The product yields and the CO2 reactivity of char from the co-pyrolysis are greatly influenced by the type of feedstock. The synergy in the presence of LS with high holocellulose and ash content is more significant than that in the presence of SD. The liquid yield of high rank TF co-pyrolysis is higher than that of low rank DY coal. The char reactivity can be improved by the co-pyrolysis at specific conditions. The co-pyrolysis in presence of DY can improve the reactivity of the produced char.
Keywords:biomass  coal  co-pyrolysis  
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