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离子选择电极法测定生活饮用水中氟化物
引用本文:胡红美,郭远明,孙秀梅,钟 志,金彩杏,尤炬炬.离子选择电极法测定生活饮用水中氟化物[J].中国无机分析化学,2013,3(3):13-16.
作者姓名:胡红美  郭远明  孙秀梅  钟 志  金彩杏  尤炬炬
作者单位:浙江省海洋水产研究所,浙江省海洋水产研究所,浙江省海洋水产研究所,浙江省海洋水产研究所,浙江省海洋水产研究所,浙江省海洋水产研究所
基金项目:2012年度省重大科技成果专项计划项目(No. 2012C13005), 浙江省科技计划项目2012F20026
摘    要:采用离子选择电极法对生活饮用水中氟化物浓度进行了测定。讨论了水样中pH值、温度、响应时间对测定结果的影响。在最佳条件下,方法的线性范围为0.10~3.0mg/L,相关系数为0.9999,检出限为0.05mg/L,实际水样加标回收率为97%~106%,相对标准偏差(n=5)为0.04%~0.65%。方法简单快速,干扰小,重现性好,加标回收率令人满意,能进行生活饮用水中氟化物浓度的有效测定。

关 键 词:离子选择电极法  生活饮用水  氟化物
收稿时间:2013/3/11 0:00:00
修稿时间:2013/3/25 0:00:00

Determination of Fluoride in Drinking Water by Ion Selective Electrode Method
HU Hongmei,GUO Yuanming,SUN Xiumei,ZHONG Zhi,JIN Caixing and YOU Juju.Determination of Fluoride in Drinking Water by Ion Selective Electrode Method[J].Chinese Journal of Inorganic Analytical Chemistry,2013,3(3):13-16.
Authors:HU Hongmei  GUO Yuanming  SUN Xiumei  ZHONG Zhi  JIN Caixing and YOU Juju
Institution:Marine Fishery Institute of Zhejiang Province,Zhejiang Province Key Lab of Mariculture Enhancement,Marine Fishery Institute of Zhejiang Province,Zhejiang Province Key Lab of Mariculture Enhancement,Marine Fishery Institute of Zhejiang Province,Zhejiang Province Key Lab of Mariculture Enhancement,Marine Fishery Institute of Zhejiang Province,Zhejiang Province Key Lab of Mariculture Enhancement,Marine Fishery Institute of Zhejiang Province,Zhejiang Province Key Lab of Mariculture Enhancement,Marine Fishery Institute of Zhejiang Province,Zhejiang Province Key Lab of Mariculture Enhancement
Abstract:A method for determination of fluoride in drinking water determined by ion selective electrode method was assessed. The influences of pH value of water samples, temperature, response time on results were discussed. Under the optimized condition, the linearity of the method was ranged from 0.10 to 3.0 mg.L-1, with a correlation coefficient of -0.9999. The limit of detection was 0.05 mg.L-1. The recoveries of real water samples were 97~106% with the relative standard deviation of 0.04~0.65% (n=5). The proposed method was simple, rapid, little interference, a satisfactory recovery with high reproducibility, and could be successfully applied for the determination of fluoride in drinking water samples.
Keywords:Ion selective electrode method  Drinking water  Fluoride
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