The formation of ReS(2) inorganic fullerene-like structures containing Re(4) parallelogram units and metal-metal bonds |
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| Authors: | Coleman Karl S Sloan Jeremy Hanson Neal A Brown Gareth Clancy Gerald P Terrones Mauricio Terrones Humberto Green Malcolm L H |
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| Institution: | Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, U.K., OX1 3QR. karl.coleman@chem.ox.ac.uk |
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| Abstract: | The encapsulation of ReO(x) within ReS(2) inorganic fullerene-like cages is described for the first time. The encapsulate was prepared by the sulfidization of both hand-milled and ball-milled samples of ReO(2); partial conversion of the oxide to the sulfide was achieved with the degree of sulfidization depending on the exposure to the sulfidizing agent, H(2)S. |
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