Structure, thermal behavior, and IR investigation of bis(3-amino-1,2,4-triazolium)monohydrogen monophosphate |
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| Authors: | Leïla Baouab Taha Guerfel Monia Soussi Amor Jouini |
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| Affiliation: | (1) Laboratoire de Chimie du Solide, Département de Chimie, Faculté des Sciences de Monastir, Université du centre, 5019 Monastir, Tunisia, North Africa |
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| Abstract: | Chemical preparation, calorimetric studies, crystal structure, and IR spectrometric investigation of (C2H5N4)2HPO4, denoted ATZP, are described. The compound crystallizes in the monoclinic system with C2/c space group. Its unit cell dimensions are a = 13.589(2) Å b = 11.105(2) Å c = 15.734(3) Å  = 104.68(2)°, V = 2296.8(7) Å3, and Z = 8. The structure of the title compound consists of a three dimensional network of H-bonds connecting all its components. The IR spectrum of ATZP is reported and discussed on the basis of group theoretical analysis. |
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| Keywords: | organic phosphate crystal structure DTA/TG/DSC IR spectra |
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