Oxidation and reductive bromination of Bis(4-tert-butylphenyl)aminoxyl |
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| Authors: | V. A. Golubev V. D. Sen’ |
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| Affiliation: | 1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia
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| Abstract: | One-electron oxidation of bis(4-tert-butylphenyl)aminoxyl with antimony pentachloride and bromine leads to the formation of oxoammonium salts with anions SbCl 6 ? and Br 3 ? respectively. The salt with the Br 3 ? anion converted at heating into a mixture of bromodiphenylamines which formed also from the aminoxyl as a result of previously unknown reaction of three-electron reductive bromination. The mechanisms of these reactions were assumed. |
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