Recombination of polyatomic ester peroxy radicals in solution |
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Authors: | S. L. Khursan V. S. Martemianov R. L. Safiullin N. S. Baisheva G. S. Ismagilova |
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Affiliation: | (1) Institute of Chemistry, State University, 450054 Ufa;(2) Permian Branch, State Institute of Applied Chemistry, 614034 Perm, USSR |
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Abstract: | Termination rate constants of peroxy radicals of seven polyatomic esters in benzene and perflouorooctane media have been measured by pulse photolysis. Recombination of peroxy radicals for all esters examined proves to be diffusion controlled. Reactivity of peroxy radicals in the termination reaction grows with increasing number of ester groups.
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