Recombination of polyatomic ester peroxy radicals in solution |
| |
Authors: | S L Khursan V S Martemianov R L Safiullin N S Baisheva and G S Ismagilova |
| |
Institution: | (1) Institute of Chemistry, State University, 450054 Ufa;(2) Permian Branch, State Institute of Applied Chemistry, 614034 Perm, USSR |
| |
Abstract: | Termination rate constants of peroxy radicals of seven polyatomic esters in benzene and perflouorooctane media have been measured by pulse photolysis. Recombination of peroxy radicals for all esters examined proves to be diffusion controlled. Reactivity of peroxy radicals in the termination reaction grows with increasing number of ester groups.
![Mcy](/content/j3610625651m1737/xxlarge1052.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![tcy](/content/j3610625651m1737/xxlarge1090.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![dcy](/content/j3610625651m1737/xxlarge1076.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![mcy](/content/j3610625651m1737/xxlarge1084.gif) ![pcy](/content/j3610625651m1737/xxlarge1087.gif) ![ucy](/content/j3610625651m1737/xxlarge1091.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![softcy](/content/j3610625651m1737/xxlarge1100.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![gcy](/content/j3610625651m1737/xxlarge1075.gif) ![fcy](/content/j3610625651m1737/xxlarge1092.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![tcy](/content/j3610625651m1737/xxlarge1090.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![zcy](/content/j3610625651m1737/xxlarge1079.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![zcy](/content/j3610625651m1737/xxlarge1079.gif) ![mcy](/content/j3610625651m1737/xxlarge1084.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![tcy](/content/j3610625651m1737/xxlarge1090.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![tcy](/content/j3610625651m1737/xxlarge1090.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![tcy](/content/j3610625651m1737/xxlarge1090.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![tscy](/content/j3610625651m1737/xxlarge1094.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![gcy](/content/j3610625651m1737/xxlarge1075.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![bcy](/content/j3610625651m1737/xxlarge1073.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![pcy](/content/j3610625651m1737/xxlarge1087.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![softcy](/content/j3610625651m1737/xxlarge1100.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![ycy](/content/j3610625651m1737/xxlarge1099.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![dcy](/content/j3610625651m1737/xxlarge1076.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![mcy](/content/j3610625651m1737/xxlarge1084.gif) ![mcy](/content/j3610625651m1737/xxlarge1084.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![gcy](/content/j3610625651m1737/xxlarge1075.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![tcy](/content/j3610625651m1737/xxlarge1090.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![mcy](/content/j3610625651m1737/xxlarge1084.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![ycy](/content/j3610625651m1737/xxlarge1099.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![zhcy](/content/j3610625651m1737/xxlarge1078.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![ycy](/content/j3610625651m1737/xxlarge1099.gif) ![ecy](/content/j3610625651m1737/xxlarge1101.gif) ![fcy](/content/j3610625651m1737/xxlarge1092.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![dcy](/content/j3610625651m1737/xxlarge1076.gif) ![bcy](/content/j3610625651m1737/xxlarge1073.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![zcy](/content/j3610625651m1737/xxlarge1079.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![pcy](/content/j3610625651m1737/xxlarge1087.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![fcy](/content/j3610625651m1737/xxlarge1092.gif) ![tcy](/content/j3610625651m1737/xxlarge1090.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![tcy](/content/j3610625651m1737/xxlarge1090.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) . ![Rcy](/content/j3610625651m1737/xxlarge1056.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![zhcy](/content/j3610625651m1737/xxlarge1078.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![tscy](/content/j3610625651m1737/xxlarge1094.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![mcy](/content/j3610625651m1737/xxlarge1084.gif) ![bcy](/content/j3610625651m1737/xxlarge1073.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![tscy](/content/j3610625651m1737/xxlarge1094.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![pcy](/content/j3610625651m1737/xxlarge1087.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![softcy](/content/j3610625651m1737/xxlarge1100.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![ycy](/content/j3610625651m1737/xxlarge1099.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![dcy](/content/j3610625651m1737/xxlarge1076.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![vcy](/content/j3610625651m1737/xxlarge1074.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![zhcy](/content/j3610625651m1737/xxlarge1078.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![ycy](/content/j3610625651m1737/xxlarge1099.gif) ![ecy](/content/j3610625651m1737/xxlarge1101.gif) ![fcy](/content/j3610625651m1737/xxlarge1092.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![pcy](/content/j3610625651m1737/xxlarge1087.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![dcy](/content/j3610625651m1737/xxlarge1076.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![dcy](/content/j3610625651m1737/xxlarge1076.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![fcy](/content/j3610625651m1737/xxlarge1092.gif) ![fcy](/content/j3610625651m1737/xxlarge1092.gif) ![ucy](/content/j3610625651m1737/xxlarge1091.gif) ![zcy](/content/j3610625651m1737/xxlarge1079.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![ycy](/content/j3610625651m1737/xxlarge1099.gif) . ![Scy](/content/j3610625651m1737/xxlarge1057.gif) ![dcy](/content/j3610625651m1737/xxlarge1076.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![vcy](/content/j3610625651m1737/xxlarge1074.gif) ![ycy](/content/j3610625651m1737/xxlarge1099.gif) ![vcy](/content/j3610625651m1737/xxlarge1074.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![vcy](/content/j3610625651m1737/xxlarge1074.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![zcy](/content/j3610625651m1737/xxlarge1079.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![tcy](/content/j3610625651m1737/xxlarge1090.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![tscy](/content/j3610625651m1737/xxlarge1094.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![pcy](/content/j3610625651m1737/xxlarge1087.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![bcy](/content/j3610625651m1737/xxlarge1073.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![tcy](/content/j3610625651m1737/xxlarge1090.gif) ![pcy](/content/j3610625651m1737/xxlarge1087.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![dcy](/content/j3610625651m1737/xxlarge1076.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![tcy](/content/j3610625651m1737/xxlarge1090.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![mcy](/content/j3610625651m1737/xxlarge1084.gif) ![bcy](/content/j3610625651m1737/xxlarge1073.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![acy](/content/j3610625651m1737/xxlarge1072.gif) ![tscy](/content/j3610625651m1737/xxlarge1094.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![tcy](/content/j3610625651m1737/xxlarge1090.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![chcy](/content/j3610625651m1737/xxlarge1095.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![scy](/content/j3610625651m1737/xxlarge1089.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![zhcy](/content/j3610625651m1737/xxlarge1078.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![ecy](/content/j3610625651m1737/xxlarge1101.gif) ![fcy](/content/j3610625651m1737/xxlarge1092.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![ncy](/content/j3610625651m1737/xxlarge1085.gif) ![ycy](/content/j3610625651m1737/xxlarge1099.gif) ![gcy](/content/j3610625651m1737/xxlarge1075.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![ucy](/content/j3610625651m1737/xxlarge1091.gif) ![pcy](/content/j3610625651m1737/xxlarge1087.gif) ![pcy](/content/j3610625651m1737/xxlarge1087.gif) ![icy](/content/j3610625651m1737/xxlarge1080.gif) ![rcy](/content/j3610625651m1737/xxlarge1088.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![vcy](/content/j3610625651m1737/xxlarge1074.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![mcy](/content/j3610625651m1737/xxlarge1084.gif) ![ocy](/content/j3610625651m1737/xxlarge1086.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) ![iecy](/content/j3610625651m1737/xxlarge1077.gif) ![kcy](/content/j3610625651m1737/xxlarge1082.gif) ![ucy](/content/j3610625651m1737/xxlarge1091.gif) ![lcy](/content/j3610625651m1737/xxlarge1083.gif) .
|
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |