Chemiluminescence and free-radical stages of the Belousov-Zhabotinskii reaction |
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Authors: | A D Karavaev and V P Kazakov |
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Institution: | (1) Institute of Chemistry, 450054 Ufa, USSR |
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Abstract: | The profound effect of stirring on chemiluminescence of the system: bromate-malonic acid-ruthenium complexes with low ( 10–5 M) catalyst concentrations indicates the significant contribution of organic radicals R. to the oscillation mechanism. Critical radical concentration for this oscillation is R.]C<7×10–10 M.
![Ocy](/content/t84x654877737714/xxlarge1054.gif) ![bcy](/content/t84x654877737714/xxlarge1073.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![rcy](/content/t84x654877737714/xxlarge1088.gif) ![ucy](/content/t84x654877737714/xxlarge1091.gif) ![zhcy](/content/t84x654877737714/xxlarge1078.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![scy](/content/t84x654877737714/xxlarge1089.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![lcy](/content/t84x654877737714/xxlarge1083.gif) ![softcy](/content/t84x654877737714/xxlarge1100.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![ocy](/content/t84x654877737714/xxlarge1086.gif) ![vcy](/content/t84x654877737714/xxlarge1074.gif) ![lcy](/content/t84x654877737714/xxlarge1083.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![yacy](/content/t84x654877737714/xxlarge1103.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![rcy](/content/t84x654877737714/xxlarge1088.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![zhcy](/content/t84x654877737714/xxlarge1078.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![mcy](/content/t84x654877737714/xxlarge1084.gif) ![pcy](/content/t84x654877737714/xxlarge1087.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![rcy](/content/t84x654877737714/xxlarge1088.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![mcy](/content/t84x654877737714/xxlarge1084.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![shcy](/content/t84x654877737714/xxlarge1096.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![vcy](/content/t84x654877737714/xxlarge1074.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![khcy](/content/t84x654877737714/xxlarge1093.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![mcy](/content/t84x654877737714/xxlarge1084.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![lcy](/content/t84x654877737714/xxlarge1083.gif) ![yucy](/content/t84x654877737714/xxlarge1102.gif) ![mcy](/content/t84x654877737714/xxlarge1084.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![scy](/content/t84x654877737714/xxlarge1089.gif) ![tscy](/content/t84x654877737714/xxlarge1094.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![tscy](/content/t84x654877737714/xxlarge1094.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![scy](/content/t84x654877737714/xxlarge1089.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![scy](/content/t84x654877737714/xxlarge1089.gif) ![tcy](/content/t84x654877737714/xxlarge1090.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![mcy](/content/t84x654877737714/xxlarge1084.gif) : ![bcy](/content/t84x654877737714/xxlarge1073.gif) ![rcy](/content/t84x654877737714/xxlarge1088.gif) ![ocy](/content/t84x654877737714/xxlarge1086.gif) ![mcy](/content/t84x654877737714/xxlarge1084.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) -![mcy](/content/t84x654877737714/xxlarge1084.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![lcy](/content/t84x654877737714/xxlarge1083.gif) ![ocy](/content/t84x654877737714/xxlarge1086.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![ocy](/content/t84x654877737714/xxlarge1086.gif) ![vcy](/content/t84x654877737714/xxlarge1074.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![kcy](/content/t84x654877737714/xxlarge1082.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![scy](/content/t84x654877737714/xxlarge1089.gif) ![lcy](/content/t84x654877737714/xxlarge1083.gif) ![ocy](/content/t84x654877737714/xxlarge1086.gif) ![tcy](/content/t84x654877737714/xxlarge1090.gif) -![kcy](/content/t84x654877737714/xxlarge1082.gif) ![ocy](/content/t84x654877737714/xxlarge1086.gif) ![mcy](/content/t84x654877737714/xxlarge1084.gif) ![pcy](/content/t84x654877737714/xxlarge1087.gif) ![lcy](/content/t84x654877737714/xxlarge1083.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![kcy](/content/t84x654877737714/xxlarge1082.gif) ![scy](/content/t84x654877737714/xxlarge1089.gif) ![rcy](/content/t84x654877737714/xxlarge1088.gif) ![ucy](/content/t84x654877737714/xxlarge1091.gif) ![tcy](/content/t84x654877737714/xxlarge1090.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![pcy](/content/t84x654877737714/xxlarge1087.gif) ![rcy](/content/t84x654877737714/xxlarge1088.gif) ![mcy](/content/t84x654877737714/xxlarge1084.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![lcy](/content/t84x654877737714/xxlarge1083.gif) ![ycy](/content/t84x654877737714/xxlarge1099.gif) ( 10–5 M) ![kcy](/content/t84x654877737714/xxlarge1082.gif) ![ocy](/content/t84x654877737714/xxlarge1086.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![tscy](/content/t84x654877737714/xxlarge1094.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![tcy](/content/t84x654877737714/xxlarge1090.gif) ![rcy](/content/t84x654877737714/xxlarge1088.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![tscy](/content/t84x654877737714/xxlarge1094.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![yacy](/content/t84x654877737714/xxlarge1103.gif) ![kcy](/content/t84x654877737714/xxlarge1082.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![tcy](/content/t84x654877737714/xxlarge1090.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![lcy](/content/t84x654877737714/xxlarge1083.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![zcy](/content/t84x654877737714/xxlarge1079.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![tcy](/content/t84x654877737714/xxlarge1090.gif) ![ocy](/content/t84x654877737714/xxlarge1086.gif) ![rcy](/content/t84x654877737714/xxlarge1088.gif) . ![Pcy](/content/t84x654877737714/xxlarge1055.gif) ![ocy](/content/t84x654877737714/xxlarge1086.gif) ![lcy](/content/t84x654877737714/xxlarge1083.gif) ![ucy](/content/t84x654877737714/xxlarge1091.gif) ![chcy](/content/t84x654877737714/xxlarge1095.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![ycy](/content/t84x654877737714/xxlarge1099.gif) ![dcy](/content/t84x654877737714/xxlarge1076.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![ycy](/content/t84x654877737714/xxlarge1099.gif) ![scy](/content/t84x654877737714/xxlarge1089.gif) ![vcy](/content/t84x654877737714/xxlarge1074.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![dcy](/content/t84x654877737714/xxlarge1076.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![tcy](/content/t84x654877737714/xxlarge1090.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![lcy](/content/t84x654877737714/xxlarge1083.gif) ![softcy](/content/t84x654877737714/xxlarge1100.gif) ![scy](/content/t84x654877737714/xxlarge1089.gif) ![tcy](/content/t84x654877737714/xxlarge1090.gif) ![vcy](/content/t84x654877737714/xxlarge1074.gif) ![ucy](/content/t84x654877737714/xxlarge1091.gif) ![yucy](/content/t84x654877737714/xxlarge1102.gif) ![vcy](/content/t84x654877737714/xxlarge1074.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![zhcy](/content/t84x654877737714/xxlarge1078.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![ocy](/content/t84x654877737714/xxlarge1086.gif) ![rcy](/content/t84x654877737714/xxlarge1088.gif) ![ocy](/content/t84x654877737714/xxlarge1086.gif) ![lcy](/content/t84x654877737714/xxlarge1083.gif) ![ocy](/content/t84x654877737714/xxlarge1086.gif) ![rcy](/content/t84x654877737714/xxlarge1088.gif) ![gcy](/content/t84x654877737714/xxlarge1075.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![chcy](/content/t84x654877737714/xxlarge1095.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![scy](/content/t84x654877737714/xxlarge1089.gif) ![kcy](/content/t84x654877737714/xxlarge1082.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![rcy](/content/t84x654877737714/xxlarge1088.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![dcy](/content/t84x654877737714/xxlarge1076.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![kcy](/content/t84x654877737714/xxlarge1082.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![lcy](/content/t84x654877737714/xxlarge1083.gif) ![ocy](/content/t84x654877737714/xxlarge1086.gif) R. ![mcy](/content/t84x654877737714/xxlarge1084.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![khcy](/content/t84x654877737714/xxlarge1093.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![zcy](/content/t84x654877737714/xxlarge1079.gif) ![mcy](/content/t84x654877737714/xxlarge1084.gif) ![pcy](/content/t84x654877737714/xxlarge1087.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![rcy](/content/t84x654877737714/xxlarge1088.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![kcy](/content/t84x654877737714/xxlarge1082.gif) ![lcy](/content/t84x654877737714/xxlarge1083.gif) ![yucy](/content/t84x654877737714/xxlarge1102.gif) ![chcy](/content/t84x654877737714/xxlarge1095.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) : ![kcy](/content/t84x654877737714/xxlarge1082.gif) ![rcy](/content/t84x654877737714/xxlarge1088.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![tcy](/content/t84x654877737714/xxlarge1090.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![chcy](/content/t84x654877737714/xxlarge1095.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![scy](/content/t84x654877737714/xxlarge1089.gif) ![kcy](/content/t84x654877737714/xxlarge1082.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![kcy](/content/t84x654877737714/xxlarge1082.gif) ![ocy](/content/t84x654877737714/xxlarge1086.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![tscy](/content/t84x654877737714/xxlarge1094.gif) ![iecy](/content/t84x654877737714/xxlarge1077.gif) ![ncy](/content/t84x654877737714/xxlarge1085.gif) ![tcy](/content/t84x654877737714/xxlarge1090.gif) ![rcy](/content/t84x654877737714/xxlarge1088.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![tscy](/content/t84x654877737714/xxlarge1094.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![rcy](/content/t84x654877737714/xxlarge1088.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![dcy](/content/t84x654877737714/xxlarge1076.gif) ![icy](/content/t84x654877737714/xxlarge1080.gif) ![kcy](/content/t84x654877737714/xxlarge1082.gif) ![acy](/content/t84x654877737714/xxlarge1072.gif) ![lcy](/content/t84x654877737714/xxlarge1083.gif) ![ocy](/content/t84x654877737714/xxlarge1086.gif) R.]C<7×10–10M.
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