Vibrational excitation and relaxation of HBr(V = 2) state |
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Authors: | Barbara M Hopkins Hao-Lin Chen |
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Institution: | Department of Chemistry, The Catholic University of America, Washington, D.C. 20017, USA |
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Abstract: | Vibrational fluorescence from the V = 2 to the V = 1 state is observed following excitation by a pulsed HBr chemical laser. The time dependence of the fluorescence is used to determine the rate of near-resonant vibration-to-vibration energy transfer, HBr(V = 1) + HBr(V = 1) ? HBr(V = 2) + HBr(V = 0) + δE = 90 cm−1. The cross section for this reacti |
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