Photoelectron spectroscopy of transient species: The CS molecule |
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| Authors: | N. JonathanA. Morris M. OkudaD.J. Smith |
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| Affiliation: | Department of Chemistry, The University, Southampton SO9 5NH, UK; Department of Physics, The University, Southampton SO9 5NH, UK |
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| Abstract: | The vacuum ultraviolet photoelectron spectrum of the CS molecule shows the first two ionization potentials to be 11.33 eV and 12.79 eV. The associated vibrational fine structure indicates that the lowest ionization potential (IP) involves removal of an electron from the essentially non-bonding (xσ) orbital whereas the second IP involves removal of an electron from the bonding (wπ) orbital. |
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