Trichloroisocyanuric acid-promoted thiolation of phosphites by thiols |
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| Authors: | Yingying Chen Meichao Li Zhangshui Gong |
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| Affiliation: | 1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, China;2. R &3. D Department, Hangzhou Toka Ink Co. Ltd., Hangzhou Economic &4. Technological Development Area, Hangzhou, China |
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| Abstract: | Abstract A simple and convenient method for the synthesis of thiophosphates by coupling of phosphites with thiols under mild conditions has been developed. The reactions were promoted by trichloroisocyanuric acid (TCCA) and were carried out at room temperature in a one-pot two-step procedure within 20?min. A variety of substrates was tolerated in this method. Notably, both aryl and alkyl thiols could afford the corresponding thiophosphates in good yields. |
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| Keywords: | Trichloroisocyanuric acid S???P bond formation phosphites thiols |
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