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Titration Calorimetric Investigations on the Interactions of Zn(II) Porphyrin Complexes with Pyridine in Benzene and Chloroform at 298.15 K |
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| Authors: | Zielenkiewicz W. Lebedeva N. Sh. Kamiński M. Antina E. V. Vyugin A. I. |
| Affiliation: | (1) Institute of Physical Chemistry, Polish Academy of Sciences, 01-224 Warsaw, Kasprzaka, 44/52, Poland;(2) Institute of Non-Aqueous Solution Chemistry, Russian Academy of Sciences, 1 Akademicheskaya Street, 153045 Ivanovo, Russia |
| Abstract: | Titration calorimetry was used in a thermodynamic study on the interactions of pyridine with natural zinc(II) porphyrin derivatives in benzene and chloroform at 298.15 K. The ability of zinc porphyrins to coordinate to pyridine is higher in benzene than in chloroform and also depends on the molecular structure of the metalloporphyrin.This revised version was published online in November 2005 with corrections to the Cover Date. |
| Keywords: | complexation titration calorimetry Zn(II) porphyrin complexes with pyridine and benzene |
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