Regioselective (12)CO/(13)CO exchange activity of a mixed-valent Fe(ii)Fe(i) model of the H(ox) state of [FeFe]-hydrogenase |
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| Authors: | Thomas Christine M Liu Tianbiao Hall Michael B Darensbourg Marcetta Y |
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| Affiliation: | Department of Chemistry, Texas A&M University, College Station, TX 77843, USA. |
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| Abstract: | A mixed-valent Fe(ii)Fe(i) model of the H(ox) state of [FeFe]-hydrogenase is shown, under certain conditions, to exhibit regioselective (12)CO/(13)CO exchange activity similar to that observed for H(ox). |
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