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阳极溶出伏安法中表面活性剂增敏机理探讨
引用本文:李建平,周遵雄.阳极溶出伏安法中表面活性剂增敏机理探讨[J].分析科学学报,1995,11(4):40-43.
作者姓名:李建平  周遵雄
作者单位:桂林工学院应化系,福清市东皋水库管理处
摘    要:本文探讨了表面活性剂在镉的阳极溶出伏安法中的增敏机理,认为表面活性剂可使训金属的水合子或其它络离子发生部分解离,既增加了溶液中电活性络离子的深度,又使离子的扩散速度加快,从而产生增敏作用。

关 键 词:表面活性剂  伏安法  增敏机理

Enhencement Mechallism of Surfactants in Anodic Stripping Voltametry
Li Jianping,Zhou Zhunxiong.Enhencement Mechallism of Surfactants in Anodic Stripping Voltametry[J].Journal of Analytical Science,1995,11(4):40-43.
Authors:Li Jianping  Zhou Zhunxiong
Abstract:The enhencement effects of several sorractapty on the determination of Cd(2+)by anodic stripping voltametric have been investigated in this paper. The results showed that surfactants canmake a few complex ions of metal including hydrated cgmplex lop dissoiated pertly .and produced simple complex ion with less ligand.The electrode reaction rate and diffusion Velocity of simple complex are greater.
Keywords:Surfactant  Enhencement mechanism  Anedic stripping voltametry
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