Synthesis of new C60 based phosphines |
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| Authors: | Sandrine BallotNicolas Noiret |
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| Affiliation: | Ecole Nationale Supérieure de Chimie de Rennes, Synthèses et Activations de Biomolécules, CNRS UMR 6052, Institut de Chimie de Rennes, Avenue du Général Leclerc, F-35700 Rennes, France |
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| Abstract: | Two series of new phosphine derivatives based on C60 protected by borane have been synthesized and characterized. These phosphines were used for two preliminary complexation trials with [RhCl(COD)]2 and [Re(S3CPh)2(S2CPh)] to afford, respectively, the corresponding complexes [RhCl(COD)(PRPh2)] and [Re(S2CPh)3(PRPh2)]. |
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| Keywords: | fullerenes phosphine ligands rhenium rhodium |
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