Microwave-accelerated conjugate addition of aldehydes to α,β-unsaturated ketones |
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| Authors: | J.S. Yadav K. AnuradhaB.V.Subba Reddy B. Eeshwaraiah |
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| Affiliation: | Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
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| Abstract: | Aldehydes undergo smooth conjugate addition to α,β-unsaturated ketones in the presence of 5-(2-hydroxyethyl)-1,3-thiazolium halides and DBU adsorbed onto the surface of basic alumina under microwave irradiation and solvent-free conditions to afford 1,4-diketones in enhanced yields and reduced reaction times compared to conventional methods. |
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| Keywords: | conjugate addition α,β-unsaturated ketones microwave 1,4-diketones |
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