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Fluorous reverse-phase silica gel-supported Lewis acids as recyclable catalysts in water |
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| Authors: | Osamu YamazakiXiuhua Hao Akihiro YoshidaJoji Nishikido |
| Affiliation: | The Noguchi Institute, 1-8-1 Kaga, Itabashi-ku, Tokyo 173-0003, Japan |
| Abstract: | Fluorous reverse-phase silica gel (FRPSG)-supported Lewis acids which have fluorous ligands acted as effective catalysts of Baeyer-Villiger and Diels-Alder reactions in water. Direct esterification of carboxylic acid with alcohol in organic media was also catalyzed. The FRPSG-supported Lewis acids could be recycled by simple filtration after the reaction. |
| Keywords: | fluorous Lewis acid fluorous reverse-phase silica gel recycling water Baeyer-Villiger reaction Diels-Alder reaction direct esterification |
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