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Synthesis of mono-, di-, and trinitro tricarboxymethyl calix[6]arenes for the complexation of uranium(VI)
Authors:Rachid SouaneVéronique Hubscher  Zouhair AsfariFrançoise Arnaud  Jacques Vicens
Institution:UMR 7512 (CNRS-ULP), ECPM, 25 rue Becquerel, F-67087 Strasbourg Cedex 2, France
Abstract:Mono-, di-, and trinitro tricarboxymethyl calix6]arenes 3(a-c) have been synthesised and their acid-base behaviour determined by potentiometric investigations. It was shown that the nitro groups do not play a major role on the acid-base properties. Preliminary complexation of uranyl is presented.
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