A novel and stereospecific synthesis of (+)-exo-brevicomin |
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| Authors: | Sadagopan Raghavan Suju C. Joseph |
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| Affiliation: | Organic Division I, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
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| Abstract: | A novel and stereospecific synthesis of (+)-exo-brevicomin is disclosed. The key step of the reaction sequence employs the sulfinyl moiety as an intramolecular nucleophile to functionalize an alkene π-complexed to a bromonium ion. |
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| Keywords: | exo-brevicomin sulfinyl moiety internal nucleophile |
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