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A novel arylation of arylacetic acid esters using tertiary arylamines and TiCl4
Authors:Mariappan PeriasamyN. KishoreBabu  Keela Natarajan Jayakumar
Affiliation:School of Chemistry, University of Hyderabad, Central University PO, Hyderabad 500 046, India
Abstract:The reactions of arylacetic acid esters with tertiary arylamines in the presence of TiCl4 give α-arylated products in 65-90% yields, as well as 10-20% yields of the corresponding benzidines.
Keywords:diaryl acetic esters   cross coupling reactions   titanium enolates   aryltitanium
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