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CH3ReO3/H2O2 in room temperature ionic liquids: an homogeneous recyclable catalytic system for the Baeyer-Villiger reaction |
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| Authors: | Roberta Bernini Antonietta CorattiGiancarlo Fabrizi Antonella Goggiamani |
| Institution: | a Dipartimento ABAC, Università degli Studi della Tuscia, Via S. Camillo De Lellis, 01100 Viterbo, Italy b Dipartimento di Studi di Chimica e Tecnologia delle Sostanze Biologicamente Attive, Università degli Studi di Roma ‘La Sapienza’, P. le A. Moro 5, 00185 Roma, Italy |
| Abstract: | The Baeyer-Villiger oxidation of cyclic ketones can be effected by methyltrioxorhenium/hydrogen peroxide in the ionic liquid bmim]BF4. After simple extraction of the lactone with diethyl ether, the catalyst can be repeatedly recycled and efficiently reused for the lactonisation process in the same reaction medium. |
| Keywords: | Baeyer-Villiger reaction cyclic ketones lactones ionic liquids [bmim]BF4 |
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