Oxidation of alkanes catalyzed by manganese(III) porphyrin in an ionic liquid at room temperature |
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| Authors: | Zhen LiChun-Gu Xia Chuan-Zhi Xu |
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| Affiliation: | State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China |
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| Abstract: | Efficient oxidation of alkanes is achieved by using an electron-deficient manganese(III) porphyrin catalyst in combination with iodobenzene diacetate in an ionic liquid at room temperature; a high-valent manganese-oxo porphyrin complex (MnVO) was considered as the reactive oxidation intermediate. |
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| Keywords: | oxidation ionic liquid manganese porphyrin |
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