SbCl5-wet acetonitrile: a new system for chemoselective O-desilylation |
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| Authors: | Paulo M.C. Gló riaSundaresan Prabhakar,Ana M. LoboMá rio J.S. Gomes |
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| Affiliation: | Paulo M.C. GlóriaSundaresan Prabhakar,Ana M. LoboMário J.S. Gomes (in part) |
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| Abstract: | A new efficient method for deprotection of TBDMS derivatives of phenols, primary alcohols, carboxylic acids and secondary amines, consisting of SbCl5 and MeCN with 0.1% water (w/v), is reported. It effects inter alia desilylation of a CH2OTBDMS group in the presence of a ketal function. |
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