Cavitands bearing four fluorophores |
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Authors: | Moonhor Ree Jong-Seong KimJae Jung Kim Byeang Hyean KimJuyoung Yoon Heesoo Kim |
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Institution: | a Department of Chemistry, Center for Integrated Molecular Systems, Division of Molecular and Life Sciences, and BK21 Program, Pohang University of Science and Technology, Pohang 790-784, Republic of Korea b Department of Chemistry, Ewha Womans University, Daeshing-dong, Seodaemoon-gu, Seoul 120-750, Republic of Korea c Department of Microbiology, Dongguk University College of Medicine, 707 Seokjang-dong, Gyeongju 780-714, Republic of Korea |
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Abstract: | The synthesis of novel cavitands containing four fluorophores tert-butoxycarbonyl protected 2,2′-bis(furyl)benzidine (t-BOC FurylBz) or 5,5′-bis(4-aminophenyl)-2,2′-bifuryl (t-BOC PFDA)] and ionophoric functional groups on the upper rim is reported. The cavitands bearing the four fluorophores emit blue light photoluminescence. In particular, the cavitand containing PFDA moieties exhibits a high photoluminescence quantum yield. |
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Keywords: | cavitands fluorophores absorption photoluminescence blue light emit quantum yield receptor dual functionalities |
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