Methylation of 1,8-dihydroxy-9,10-anthraquinone with and without use of solvent-free technique |
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Authors: | Grigoriy A. SeredaDavid G. Akhvlediani |
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Affiliation: | University of South Dakota, Department of Chemistry, 414 E. Clark Street, Vermillion, SD 57069, USA |
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Abstract: | A convenient and environmentally friendly solvent-free procedure has been developed for dimethylation of 1,8-dihydroxy-9,10-anthraquinone with excellent yield. A highly selective monomethylation of 1,8-dihydroxy-9,10-anthraquinone in refluxing tetraglyme makes monomethylated peri-dihydroxy-9,10-anthraquinones easily available. Alternatively, irradiation in a domestic microwave oven has been employed for the solvent-free monomethylation of 1,8-dihydroxy-9,10-anthraquinone. |
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