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Enantiopure hydroxylactones from d-xylose. A novel approach to the enantiodivergent synthesis of (+)- and (−)-muricatacin suitable for the preparation of 7-oxa analogues |
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| Authors: | Velimir Popsavin Ivana Krsti?Mirjana Popsavin |
| Abstract: | A new route towards enantiopure hydroxylactones 3 and ent-3, the final chiral precursors in an enantiodivergent synthesis of (+)- and (−)-muricatacin, has been developed starting from d-xylose. |
| Keywords: | 5-hydroxyalkylbutan-4-olides d-xylose" target="_blank">d-xylose muricatacin enantiodivergent synthesis Wittig reaction |
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