Lanthanide assisted cross-coupling of aryl bromides with triethylaluminum |
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| Authors: | Margarita ShenglofDmitri Gelman Gary A MolanderJochanan Blum |
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| Affiliation: | a Department of Organic Chemistry, The Hebrew University, Jerusalem 91904, Israel
b Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania, PA 19104-6323, USA |
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| Abstract: | Cerium trichloride, as well as some other lanthanide salts, promote the palladium-catalyzed cross-coupling of triethylaluminum with bromoarenes. The lanthanide compounds also increase the selectivity by diminishing the undesired hydrodebromination process. |
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| Keywords: | aluminum bromoarenes cross-coupling lanthanide compounds |
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