A new and highly effective method for catalytic oxidation of alcohols to the corresponding carbonyl compounds using the tris[(2-oxazolinyl)phenolato]manganese(III)/Oxone®/n-Bu4NBr oxidation system |
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Authors: | Mojtaba Bagherzadeh |
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Affiliation: | Department of Chemistry, Sharif University of Technology, PO Box 11395-9516, Tehran, Iran |
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Abstract: | Oxone® (2KHSO5·KHSO4·K2SO4) in the presence of mer-tris[(2-oxazolinyl)phenolato]manganese(III), Mn(phox)3, as catalyst under biphasic reaction conditions (CH2Cl2/H2O) and tetra-n-butylammonium bromide as phase transfer agent efficiently oxidises alcohols to their corresponding aldehydes and ketones at room temperature with very short reaction times (5 min) and good to quantitative yields. |
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Keywords: | Mn-oxazoline complex alcohol catalytic oxidation Oxone® |
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