A new and highly effective method for catalytic oxidation of alcohols to the corresponding carbonyl compounds using the tris[(2-oxazolinyl)phenolato]manganese(III)/Oxone®/<em>n</em>-Bu<sub>4</sub>NBr oxidation system期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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A new and highly effective method for catalytic oxidation of alcohols to the corresponding carbonyl compounds using the tris[(2-oxazolinyl)phenolato]manganese(III)/Oxone®/n-Bu₄NBr oxidation system

Authors:	Mojtaba Bagherzadeh

Institution:	Department of Chemistry, Sharif University of Technology, PO Box 11395-9516, Tehran, Iran

Abstract:	Oxone® (2KHSO₅·KHSO₄·K₂SO₄) in the presence of mer-tris(2-oxazolinyl)phenolato]manganese(III), Mn(phox)₃, as catalyst under biphasic reaction conditions (CH₂Cl₂/H₂O) and tetra-n-butylammonium bromide as phase transfer agent efficiently oxidises alcohols to their corresponding aldehydes and ketones at room temperature with very short reaction times (5 min) and good to quantitative yields.

Keywords:	Mn-oxazoline complex alcohol catalytic oxidation Oxone®
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