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A new and highly effective method for catalytic oxidation of alcohols to the corresponding carbonyl compounds using the tris[(2-oxazolinyl)phenolato]manganese(III)/Oxone®/n-Bu4NBr oxidation system
Authors:Mojtaba Bagherzadeh
Institution:Department of Chemistry, Sharif University of Technology, PO Box 11395-9516, Tehran, Iran
Abstract:Oxone® (2KHSO5·KHSO4·K2SO4) in the presence of mer-tris(2-oxazolinyl)phenolato]manganese(III), Mn(phox)3, as catalyst under biphasic reaction conditions (CH2Cl2/H2O) and tetra-n-butylammonium bromide as phase transfer agent efficiently oxidises alcohols to their corresponding aldehydes and ketones at room temperature with very short reaction times (5 min) and good to quantitative yields.
Keywords:Mn-oxazoline complex  alcohol  catalytic oxidation  Oxone®  
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