Mechanochemical synthesis of a novel C60 dimer connected by a germanium bridge and a single bond |
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Authors: | Yasujiro MurataAihong Han Koichi Komatsu |
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Institution: | Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan |
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Abstract: | A novel C60 dimer connected by a germanium bridge and a single bond was synthesized by the mechanochemical solid-state reaction using a high-speed vibration milling technique. The structural characterization was made by the 1H and 13C NMR, APCI mass, and UV-vis spectroscopy, and the presence of the electronic interaction between the two C60 cages was demonstrated by the electrochemical method. |
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Keywords: | fullerene C60 germanium solid-state reaction high-speed vibration milling |
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