Sterically congested ‘roofed’ 2-thiazolines as new chiral ligands for copper(II)-catalyzed asymmetric Diels-Alder reactions |
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| Authors: | Manabu Yamakuchi Ryoh Tokuda Makoto Nakajima |
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| Institution: | a Faculty of Medical and Pharmaceutical Sciences, Kumamoto University, 5-1 Oe-honmachi, Kumamoto 862-0973, Japan
b Faculty of Pharmaceutical Sciences, Sojo University, 4-22-1 Ikeda, Kumamoto 860-0082, Japan |
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| Abstract: | Newly introduced chiral ‘roofed’ 2-thiazolines, prepared from sterically congested, conformationally rigid chiral 2-aminothiols, function as efficient chiral ligands for the asymmetric Diels-Alder reaction of cyclopentadiene and 3-acryloyl-2-oxazolidinone. |
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