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Benzothiazines in synthesis. Formal synthesis of erogorgiaene
Authors:Michael Harmata  Xuechuan Hong
Institution:Department of Chemistry, University of Missouri-Columbia, Columbia, MO 65211, USA
Abstract:A benzothiazine, readily available in enantiomerically pure form via a completely selective, intramolecular addition of a sulfoximine-stabilized carbanion to an α,β-unsaturated ester, could be converted to a precursor to erogorgiaene in good overall yield.
Keywords:Benzothiazine  Sulfoximine  Anti-tubercular  Stereoselective  Erogorgiaene
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