Synthesis of bhimamycin B based on oxidative rearrangement of 4-acetylnaphtho[1,2-b]furan-5-ol to naphtho[2,3-c]furan-4,9-dione |
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| Authors: | Hidemitsu Uno Seiya Murakami Akiko Fujimoto Youtarou Yamaoka |
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| Institution: | Division of Synthesis and Analysis, Department of Molecular Science, Integrated Center for Sciences, 2-5 Bunkyo-cho, Matsuyama 790-8577, Japan |
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| Abstract: | The first total synthesis of bhimamycin B, a novel member of naphtho2,3-c]furan quinone antibiotics, was achieved by oxidative skeletal rearrangement of 4-acetylnaphtho1,2-b]furan-5-ol. |
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| Keywords: | Bhimamycin B Iodosobenzene diacetate Naphtho[2 3-c]furan |
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