Rhodium perfluorobutyramide (Rh2(pfm)4): a synthetically useful catalyst for olefin aziridinations |
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| Authors: | Gregg F Keaney |
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| Institution: | Sterling Chemistry Laboratory, Department of Chemistry, Yale University, New Haven, CT 06520-8107, USA |
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| Abstract: | Rhodium perfluorobutyramide (Rh2(pfm)4) has been shown to catalyze the conversion of olefins to trichloroethoxysulfonyl, nosyl, and tosyl aziridines. Advantages of this aziridination procedure include the microwave-assisted preparation of the catalyst and the practical use of the alkene substrate as the limiting reagent. |
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| Keywords: | Kalihinane diterpenoids Aziridination Microwave Nosyl Tosyl Trichloroethoxysulfonyl Rhodium perfluorobutyramide |
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