Stereoselective total synthesis of (+)-cryptocarya diacetate by an iterative Jacobsen’s hydrolytic kinetic resolution protocol |
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| Authors: | Palakodety Radha Krishna V.V. Ramana Reddy |
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| Affiliation: | D-206/B, Discovery Laboratory, Organic Chemistry Division-III, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
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| Abstract: | A combination of iterative Jacobsen’s hydrolytic kinetic resolution and reduction of a ketone for the construction of a 1,3-polyol moiety are key steps en route to a total synthesis of (+)-cryptocarya diacetate. |
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| Keywords: | Jacobsen hydrolytic kinetic resolution α,β-unsaturated δ-lactone 1,3-syn-polyol |
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