A new tricyclic triketone from tandem condensation reactions |
| |
| Authors: | I. David Reingold,Anna M. Butterfield,Robert S. Walters Jr.,Susan Scheuring,Milan Gembický ,Peter Baran |
| |
| Affiliation: | a Department of Chemistry, Juniata College, Huntingdon, PA 16652, USA
b Department of Chemistry, SUNY Buffalo, Buffalo, NY 14260-3000, USA |
| |
| Abstract: | Perhydrophenanthrene-1,5,10-trione (6) was isolated from the reaction of methyl 3-(carboxymethyl)cyclohexanone and cyclohexenone in a tandem Michael-Claisen reaction. NMR and X-ray analysis confirmed the structure of the product. |
| |
| Keywords: | Michael Claisen Tricyclic Triketone Modeling Tandem condensations Kekulene Perhydrophenanthrene |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
